Spectroscopic Measurement of Hydrogen Contamination in Weld Arc Plasmas
by
J. E. Shea
C. S. Gardner
Radio Research Laboratory
Department of Electrical Engineering
Abstract
The introduction of hydrogen into metals during welding is known to cause hydrogen assisted cracking and embrittlement in certain situations. It has been shown that the weld metal hydrogen content is directly related to hydrogen concentration in the weld arc plasma. In this paper we describe a simple spectroscopic technique for measuring the arc plasma hydrogen concentration in real time when an argon shield gas is used. This technique is based on the fact that the intensity ratio of the hydrogen Balmer Alpha emission line at 6563Å and an argon emission line at 6965Å was observed to an approximately linear function of hydrogen concentration in the weld arc plasma. This technique was experimentally verified under a variety of welding conditions for gas metal arc welding and found to have an error of less than 10% when measuring hydrogen concentrations in the arc plasma as low as 0.25% by volume. This method of hydrogen measurement is also applicable when welding with shield gases not containing argon so long as a suitable ratioing line is available.
PACS numbers: 52.70.Kz, 07.65.EH, 52.80.Mg, 81.40Np
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